The 185-nm photochemistry of bicyclo[2.1.0]pentane and cyclopentene
β Scribed by Adam, Waldemar; Oppenlaender, Thomas
- Book ID
- 119956665
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 604 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
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Cyclobutane to diolefin trausfcmations prauoted by transition-metal compounds, such as 1-s the isomerisation of quadricyclaues to norbornadienes and of cube type moleculestoring cleaved products, 495 have recently attracted cmsiderable attention. Lately, we' and The details of the preparation of th
The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mecha