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The 1,4-addition of organometallic reagents to enoates derived from pinanediol

✍ Scribed by Sergio Pinheiro; Sérgio F. Pedraza; Mônica A. Peralta; Rafael C. Teixeira; Florence M.C. de Farias; Vı́tor F. Ferreira; Paulo R.R. Costa

Book ID
104359516
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
199 KB
Volume
13
Category
Article
ISSN
0957-4166

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✦ Synopsis

The complex-induced, proximity effect-promoted 1,4-addition of RCu•BF 3 and R 2 CuLi to enoates derived from (-)-pinanediol leads to adducts with the opposite sense of chirality (up to 98% d.e.).

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