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The 13C NMR spectra of cyclopentadienylides and their complexes with the group vi metal carbonyls

✍ Scribed by V.N. Setkina; A.Zh. Zhakaeva; G.A. Panosyan; V.I. Zdanovitch; P.V. Petrovskii; D.N. Kursanov

Book ID
108353994
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
509 KB
Volume
129
Category
Article
ISSN
0022-328X

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✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo