The 13C NMR spectra and structure of 2,1,3-benzoxadiazole,-benzothiadiazole and -benzoselenadiazole
β Scribed by G. W. H. Cheeseman; C. J. Turner
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 241 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0749-1581
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β¦ Synopsis
Abstract
The ^13^C NMR chemical shifts and oneβbond carbonβhydrogen coupling constants have been obtained for the title compounds in carbon disulphide as solvent. There appears to be little solvent effect on the ^13^C chemical shifts. The results suggest the order of release of electrons into the ring is O β« S > Se.
π SIMILAR VOLUMES
A set of 3-alkylaminoacroleins (R1NHCHxCHCHxO, R1 \ alkyl) were studied by 13C and 1H NMR spectroscopy in solutions of di β erent solvents and, for the simplest representative of the series, 3methylaminoacrolein, at di β erent temperatures. The equilibrium solutions of these compounds consists of mixt