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The 1,3-Dithian-2-ylmethoxycarbonyl (Dmoc) Moiety–A Protecting Group for the Amino Function in Peptide Synthesis

✍ Scribed by Regina Barthels; Prof. Dr. Horst Kunz

Book ID
111698445
Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
111 KB
Volume
21
Category
Article
ISSN
0044-8249

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✍ H. C. Beyerman; J. S. Bontekoe 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 378 KB

## Abstract We have found a novel way of protecting the hydroxyl function in hydroxy‐L‐amino acids, making use of the t‐butoxy group, which is readily split by acids, but not by bases. This group is introduced by acid‐catalysed addition of isobutene to N‐acylated hydroxy‐L‐amino acids. The blockin