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The 1:1 proton-transfer compound of 8-quinolinol (oxine) with pyrazine-2,3-dicarboxylic acid: 8-hydroxy­quinolinium 3-carboxy­pyrazine-2-carboxyl­ate dihydrate

✍ Scribed by Smith, Graham ;Wermuth, Urs D. ;Healy, Peter C. ;White, Jonathan M.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
204 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The asymmetric unit of the title compound, C 9 H 8 NO + ÁC 6 H 3 -N 2 O 4 À Á2H 2 O, contains two independent cations, two anions and four water molecules of solvation. A three-dimensional framework structure is formed through extensive hydrogenbonding involving most donor and acceptor species. Significant aromatic C-HÁ Á ÁO and cation-cationinteractions are also present.