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Thallium in organic synthesis. 44. Oxidative rearrangements via oxythallation with thallium(III) nitrate supported on clay

✍ Scribed by Taylor, Edward C.; Chiang, Chih-Shu; McKillop, A.; White, J. F.

Book ID: 126081764
Publisher: American Chemical Society
Year: 1976
Tongue: English
Weight: 348 KB
Volume: 98
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00437a082

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We have recently described 3-5 a number of TTN-mediated oxidations of styrene derivatives which proceed extremely rapidly at room temperature to give high yields of carbonyl compounds. The overall transformation is