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Thallium Halides — New Aspects of the Stereochemical Activity of Electron Lone Pairs of Heavier Main-Group Elements

✍ Scribed by Anja-Verena Mudring

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Thallium Halides – New Aspects of the St
Thallium Halides – New Aspects of the Stereochemical Activity of Electron Lone Pairs of Heavier Main-Group Elements
✍ Anja-Verena Mudring 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB

## Abstract Density functional theory studies in the linear muffin tin approximation on thallium halides (TlX; X = F, Cl, Br, I) show that structural distortions due to a stereochemically active lone pair of electrons depend crucially on cation–anion interactions. Such distortions do not originate

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## Abstract The syntheses and structures of complexes of the fifth period elements indium and antimony, and the sixth period element bismuth with the soft scorpionate ligand, hydrotris(methimazolyl)borate (Tm^Me^) are reported. A considerable variety of structural motifs were obtained by reaction o