✦ LIBER ✦
Tetrathiophosphoric acid tri(1-phenylethyl) ester and1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents
✍ Scribed by Didier Gigmes; Denis Bertin; Sylvain Marque; Olivier Guerret; Paul Tordo
- Book ID
- 104252908
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 179 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Polystyrene and polystyrene-b-polyvinylacetate have been prepared in presence of either tetrathiophosphoric acid tri(1-phenylethyl) ester 1 or 1-phenylethyl-diphenylphosphinodithioate 2 under radical conditions. From kinetic studies performed with or without 1 or 2, it was shown that the polymerization presents the criteria of living/controlled polymerization.