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Tetrathiafulvalene. XX. Charge-Transfer, Radikalkonzentration und elektrische Eigenschaften von TTF und TSF-TCNQ-Komplexen

✍ Scribed by Prof. Dr. E. Fanghänel; Dr. G. Schukat; Dipl.-Chem. J. Schützendübel; SDipl.-Chem. W. Humsch

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
227 KB
Volume
325
Category
Article
ISSN
1615-4150

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✦ Synopsis

Tetrathiafulvalenes XX. Charge‐Transfer, Radical Concentration and Electrical Properties of TTF‐ and TSF‐TCNQ‐Complexes

For TTF‐TCNQ‐complexes the spin density increases with a higher degree of CT, estimated from the value of C‐N‐vibration in TNCQ. The dihydronaphthocondensed cis‐ and trans‐TSF‐TCNQ‐complexes (11, 12) show the same high conductivity, whether the complex composition is 2:1 or 1:1.

📜 SIMILAR VOLUMES

Tetrathiafulvalene. XVI. Spektroskopisch
Tetrathiafulvalene. XVI. Spektroskopische und elektrische Eigenschaften von TTF und TTF-TCNQ-Komplexen
✍ Dr. G. Schukat; Prof. Dr. E. Fanghänel; Dr. A. Chyla 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 373 KB

**Tetrathiafulvalenes. XVI. Spectroscopic and Electrical Properties of TTF and TTF‐TCNQ‐Complexes** UV‐vis‐spectra of mono‐ and dications of the TTF **2** show in comparison to those of TTF **1** and **3** that the aryl substituent in the TTF **2** is more twisted from the TTF‐plane than in **1** a