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Tetrathiafulvalene-based lanthanide coordination complexes: Synthesis, crystal structure, optical and electrochemical characterization

✍ Scribed by Ying-Fen Ran; Martin Steinmann; Marc Sigrist; Shi-Xia Liu; Jürg Hauser; Silvio Decurtins

Book ID
119222795
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
731 KB
Volume
15
Category
Article
ISSN
1631-0748

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4-[2-tetrathiafulvalenyl-ethenyl]pyridine (1) has been prepared from a Wittig reaction between formyltetrathiafulvalene and 4-picolyltriphenylphosphonium chloride hydrochloride. Conversion of the pyridine moiety of 1 by reaction with methyl iodide leads to 4-[2-tetrathiafulvalenyl-ethenyl]-1-methylp