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Tetraphenylarsonium 1,2,3,4,5-pentakis(methylmercapto)cyclopentadienide

✍ Scribed by Wudl, F.; Nalewajek, D.; Rotella, F. J.; Gebert, E.

Book ID
127161127
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
763 KB
Volume
103
Category
Article
ISSN
0002-7863

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✍ Hartke, Klaus ;Kraska, Andreas ;Massa, Werner ;Molinier, Michel ;Wocadlo, Sigrid πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 913 KB

## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit