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Tetranuclear rhenium chalcogenide cluster complexes with a cubane core. Synthesis, structures, and properties

✍ Scribed by Yu. V. Mironov; V. E. Fedorov

Book ID: 110341736
Publisher: Springer
Year: 2002
Tongue: English
Weight: 536 KB
Volume: 51
Category: Article
ISSN: 1573-9171
DOI: 10.1023/a:1015843529164

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## Abstract The reaction between [(tbbpy)~2~Ru(tmbiH~2~)](PF~6~)~2~ (tbbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine; tmbiH~2~ = 5,5′,6,6′‐tetramethyl‐2,2′‐dibenzimidazole) and LiMe/CuI affords the tetranuclear complex 1 containing the dication [{(tbbpy)~2~Ru(tmbi)}~2~Cu~2~]^2+^. The X‐ray structure