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Tetranuclear Copper(I)-Biphenanthroline Gridwork: Violation of the Principle of Maximal Donor Coordination Caused by Intercalation and CH-to-N Forces

✍ Scribed by Shinji Toyota; Craig R. Woods; Maurizio Benaglia; Richard Haldimann; Kenneth Wärnmark; Kenneth Hardcastle; Jay S. Siegel


Book ID
101366561
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
115 KB
Volume
113
Category
Article
ISSN
0044-8249

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Tetranuclear Copper(I)-Biphenanthroline
✍ Shinji Toyota; Craig R. Woods; Maurizio Benaglia; Richard Haldimann; Kenneth Wär 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB

The amelioration of ªhot spotsº in a molecule through specific molecular association is a general chemical principle, which has been recently highlighted as a driving force for ªsupramolecularº reactions. [1] The instability of unpaired radicals, uncoordinated metal ions and ligands, and unasso-evid