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Tetramethylguanidine (TMG)-catalyzed addition of dialkyl phosphites to α,β-unsaturated carbonyl compounds, alkenenitriles, aldehydes, ketones and imines

✍ Scribed by Daniele Simoni; Francesco Paolo Invidiata; Monica Manferdini; Ilaria Lampronti; Riccardo Rondanin; Marinella Roberti; Gian Piero Pollini


Book ID
104259959
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
185 KB
Volume
39
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Tetramethylguanidin
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Enantioselective Copper-Catalyzed 1,4-Ad
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The enantioselective copper-catalyzed 1,4-addition of Grignard reagents to a$-unsaturated carbonyl compounds was studied with the following Cu' compounds as catalyst precursor and 1,2 : 5,6-di-0 -isopropylidene-3thio-a -o-glucofuranose (Hsiig) as chiral ligand: CuI, iodo[bis(dibutylsulfide)]copper(I