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Tetramethyl cyclobutadiene via irradiation of hexamethyl dewar benzene mono-ozonide

✍ Scribed by F.R. Wight


Book ID
104225722
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
230 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis


The structure of cyclobutadiene has been a topic of considerable interest.

Theoretical calculations have predicted a singlet ground state with Dzh symmetry[Zl and experimental results have generally been consistent with this structure.

[3] Recently, however, strong evidence has been presented which indicates cyclobutadiene has Dqh symmetry. [4] We report here our results on tetramethyl cyclobutadiene (TMCB) which suggest that this compound has a singlet ground state.