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Tetrameric Cubic Structures of Two Solvated Lithium Enolates

✍ Scribed by René Amstutz; W. Bernd Schweizer; Dieter Seebach; Jack D. Dunitz

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
267 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The structures of the crystalline lithium enolates derived from 3, 3‐dimethyl‐2‐butanone and from cyclopentanone have been determined by X‐ray analysis. Both structures are tetrameric aggregates based on a Li~4~O~4~‐cube, each Li^+^‐ion being additionally bonded to the O‐atom of a tetrahydrofuran solvent molecule.

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