✦ LIBER ✦
Tetralithium Bis(ethylaluminum) Tetrakis(catecholate) Pentakis(dimethoxyethane): An Oxygen-Rich Cluster [(Al++2(Li+)4(O18)−8] in a C36H44 Hydrocarbon Shell
✍ Scribed by Hans Bock; Reinhard Beck; Zdenek Havlas; Holger Schödel
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 150 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
The structure determination of the lipophilically wrapped According to density functional theory calculations, the eight negative charges are well-delocalized over the oxygen-rich cluster {[Al 2 Li 4 O 18 ](C 36 H 44 )} ϱ , a novel material crystallized from a mixture of [(C 2 H 5 ) 3 Al] 2 , nBuLi, and catechol in DME framework. solution, reveals five-coordinate Al ++ and Li + centers.