Tetrakis(hypersilyl)dithallium(TlTl): A Divalent Thallium Compound

✍ Scribed by Sonja Henkel; Dr. Karl Wilhelm Klinkhammer; Dr. Wolfgang Schwarz

• Publisher: John Wiley and Sons
• Year: 1994
• Tongue: English
• Weight: 431 KB
• Volume: 33
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.199406811

✦ Synopsis

A TlTl bond 291.4 pm in length is the prominent structural feature of the thallium(II) compound 1, the product of the reaction of RbSi(SiMe~3~)~3~ with TlN(SiMe~3~)~2~. The red compound 1, which is thermally unstable in solution, can be stored for longer periods in the solid state.
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