Tetrakis-phthalocyanines bearing electron-withdrawing fluoro functionality: Synthesis, spectroscopy, and electrochemistry

✍ Scribed by Ahmet T. Bilgiçli; Mehmet Kandaz; Ali Rıza Özkaya; Bekir Salih

• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 344 KB
• Volume: 20
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.20545

✦ Synopsis

give ligand-based reduction and oxidation processes, CoPcOBzF 16 gives both ligand and metal-based redox processes, in harmony with the common metallophthalocyanine complexes. Redox processes due to both aggregated and disaggregated species were simultaneously observed during the first reduction process. The nature of the metal-based redox processes was confirmed using spectroelectrochemical measurements.