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Tetragonally compressed high-spin Mn(III) Schiff base complex: Synthesis, crystal structure, magnetic properties and theoretical calculations

✍ Scribed by Wang, Shi; He, Wen-Rui; Ferbinteanu, Marilena; Li, Yong-Hua; Huang, Wei


Book ID
123153687
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
775 KB
Volume
52
Category
Article
ISSN
0277-5387

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~