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Tetracyclo[3.3.0.02,4.03,6]oct-7-en, ein neues valenzisomer dder familie (CH)8

✍ Scribed by Gerhard W. Klumpp; Johan Stapersma


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
120 KB
Volume
18
Category
Article
ISSN
0040-4039

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## Abstract Cyclooctatetraene is a common product of photolysis of the title compound la. Depending on reaction conditions it is accompanied by benzene (solvent: cyclohexane, Ξ³ = 253.7 nm), benzene plus semibullvalene (acetone, 300 nm), and an oxetane (cyclohexane, 350 nm, presence of an equimolar

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which is converted by cleavage of CO, into the products in a thermodynamic E/Z ratio (E/Z= 9/1). ## Tetracyclo [4.1.0.02~4.03~5)heptanes from 7,8-Diazatetracyclo14.3.0.0z~4.03~s~non-7-enes I\*\*]