The Sharpless reagent (Ti(OiPr)4 t 1 mol eq. diethyl tartrate (DET) t 2 J-BuOOH) modified by addition of one mol eq. H20 gives a new homogeneous reagent which cleanly oxidizes sulfidesinto sulfoxides in dichloromethane. The best results were obtained for the stoichiometry Ti/DET/ H20/J-BuOOH = 1:2:1
โฆ LIBER โฆ
Tetracyanoethylene Oxide Not Only Oxidizes Sulfides to Sulfoxides but also Reduces Sulfoxides to Sulfides.
โ Scribed by Juzo Nakayama; Ayako Tai; Sachiko Iwasa; Tomohiro Furuya; Yoshiaki Sugihara
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 16 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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