Tetracoordinated derivatives of 1-oxa-2-telluracyclopentane
✍ Scribed by V. L. Nivorozhkin; I. D. Sadekov; V. I. Minkin
- Book ID
- 104792752
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 96 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-3122
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## Abstract The synthesis of 7,8‐dihydroxy‐2‐(2‐methoxycarbonylethyl)‐4,9‐dioxa‐2‐azabicyclo[4.2.1]nonane‐ 3‐thione (**16**) and of its parents 9‐oxa‐4‐thia‐3‐thione **17**, and 9‐oxa‐4‐thia‐3‐one **18** is described. The conversion of 5′‐deoxy‐5′‐iodo‐2′,3′‐__O, O__‐isopropylidene‐5,6‐dihydrouridi
## Abstract magnified image Tris(dimethylsilyl)methyl lithium, (HSiMe~2~)~3~CLi, reacts with allyl, phenyl, benzyl, __n__‐propyl and __n__‐butyl glycidyl ethers in THF at ‐5 °C to give 1‐oxa‐2‐silacyclopentane derivatives. It seems that ring closure is facilitated by conversion of the SiH bond in