Tetraaquabis(2-methoxybenzaldehyde isonicotinoylhydrazone)zinc dinitrate
✍ Scribed by Gao, Shaokang ;Fu, Zhongwu ;Wang, Zengyou
- Book ID
- 104492480
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 713 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Zn(C 14 H 13 N 3 O 2 ) 2 (H 2 O) 4 ](NO 3 ) 2 , the Zn atom is located on a center of symmetry. The Zn-O bond distances are 2.0816 (19) and 2.1356 (18) A ˚, and the Zn-N bond distance is 2.166 (2) A ˚. The coordination polyhedron is a slightly distorted octahedron. The crystal structure is stabilized by O-H(coordinated water)Á Á ÁO(NO 3 À or carbonyl O) and N-H(imine)Á Á ÁO(NO 3 À ) hydrogen bonds, forming a three-dimensional network.
📜 SIMILAR VOLUMES
In the title compound, [Zn(NCS) 2 (H 2 O) 4 ]Á2C 5 H 6 N 2 O 2 , the six-coordinated Zn II atom lies on a special position of site symmetry 2/m. The methylpyrazine dioxide molecule lies on a mirror plane and links with the Zn II complex via O-HÁ Á ÁO hydrogen bonding.
In the structure of the title compound, [Zn(C 7 H 4 N 3 OS) 2 -(H 2 O) 4 ]Á2H 2 O, the Zn II atom, located on an inversion centre, is coordinated by the pyridyl groups of two oxadiazole ligands and four water molecules. The packing is dominated by a three-dimensional system of hydrogen bonds.
The title compound, [Zn(C~11~H~15~BrN~2~O)~2~](NO~3~)~2~, is a centrosymmetric mononuclear Schiff base zinc(II) complex. The Zn^II^ atom, lying on a twofold rotation axis, is four-coordinated by two phenolate O atoms and two imine N atoms from two Schiff base ligands, forming a tetrahedral coordinat