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Tetraamine complexes of chromium(III). 4. Kinetics of the aquation of the cis-aquabis(ethylenediamine)iodochromium(III) cation

✍ Scribed by Chang, James C.; Vaughn, Joe W.

Book ID: 126866214
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 410 KB
Volume: 21
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00136a084

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Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo