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Tetra oxalato complexes of uranium(IV)— M2U(C2O4)4 — nH2O

✍ Scribed by S.K. Awasthi; K.L. Chawla; D.M. Chackraburtty

Book ID
115973326
Publisher
Elsevier Science
Year
1974
Weight
197 KB
Volume
36
Category
Article
ISSN
0022-1902

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U(IV)/Ln(III) unexpected mixed site in p
U(IV)/Ln(III) unexpected mixed site in polymetallic oxalato complexes. Part I. Substitution of Ln(III) for U(IV) from the new oxalate (NH4)2U2(C2O4)5·0.7H2O
✍ Benedicte Chapelet-Arab; Guy Nowogrocki; Francis Abraham; Stephane Grandjean 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 443 KB

A new ammonium uranium (IV) oxalate (NH 4 ) 2 U 2 (C 2 O 4 ) 5 Á 0.7H 2 O (1) and three mixed uranium (IV)-lanthanide (III) oxalates, 4) and Na 3 UCe (C 2 O 4 ) 5 Á 10.4H 2 O (5), have been prepared. The crystal structures of compounds 1, 4 and 5 have been determined by singlecrystal X-ray diffracti