Tetra-n-butylammonium tetrakis(pentafluorophenyl)borate
✍ Scribed by Schödel, Frauke ;Lerner, Hans-Wolfram ;Bru Roig, Miriam ;Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 183 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 16 H 36 N + ÁC 24 BF 20 À , the geometric parameters do not show any unusual values. The four n-butyl chains adopt an all-trans conformation.
📜 SIMILAR VOLUMES
The title compound, Li + ÁC 24 BF 20 À Á2C 6 H 6 , crystallizes as centrosymmetric dimers, with two 6 -coordinated and two uncoordinated molecules of benzene per dimer. There are two crystallographically independent dimers.
In the title compound, C 4 H 11 BrN + ÁBF 4 À , both ions lie on crystallographic mirror planes, and the compound is isomorphous with the chloromethyl analog. The C-Br distance is 1.927 (2) A ˚.
The structure of the title compound, C 16 H 36 N + ÁPF 6 À , has been reported previously by Angaridis, Cotton & Petrukhina [Inorg. Chim. Acta (2001), 324, 318±323]. However, these authors found the PF 6 À ion to be heavily disordered and they did not publish any coordinates. We present here a redet
The receptor of the title compound, C 14 H 36 N + ÁCl À Á-C 20 H 14 N 4 O 6 , binds a chloride anion via two N-HÁ Á ÁCl hydrogen bonds [NÁ Á ÁCl = 3.2367 (14) A ˚and 3.3239 ( 15) ].