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Testing free volume theory for penetrant diffusion in rubbery polymers

✍ Scribed by M.P Tonge; R.G Gilbert


Book ID
108366215
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
225 KB
Volume
42
Category
Article
ISSN
0032-3861

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## Abstract In the framework of the free‐volume (FV) theory, a new equation was derived for the evaluation of self‐diffusion coefficients of small molecules in polymers above the mixture glass transition temperature. The derivation of the equation turned out to be straightforward once the equivalen