Tertiary Acetylenic Alcohols and Peroxides Derived from 4,4'-Bis(dimethylamino)benzophenone (Michler's Ketone)

Unusual solvatochromism of the 4,4′-bis(

Unusual solvatochromism of the 4,4′-bis(dimethylamino)benzophenone (Michler's ketone)–tetracyanoethene electron donor–acceptor complex

✍ Stefan Spange; Elmar Vilsmeier; Simone Adolph; Annett Fährmann 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB

The transition energy of the charge-transfer UV/Vis absorption maxima (# max, CT ) and the structure of the Michler's ketone (MK)-tetracyanoethene (TCNE) electron donor-acceptor (EDA) complex are remarkably solvent dependent. The UV/Vis spectra of the MK-TCNE complex were measured in 20 non-protic a