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Terpene ethers VII. New products from the reaction of 3-carene with formaldehyde

✍ Scribed by Jan Chlebicki; Bogdan Burczyk

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
169 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

There are only few papers in the literature dealing with the reaction oi 3-carens with formaldehyde. I-4 Without catalysts this reaction yields 3-hydroxymethyl-4-carene /IV/ as main product together rith small amount oi 3-hydroxymethyl-4/10/-carene /II/.

Studying the reaction oi 3-carene with iormaldehyde in anhydrous aoetic acid we found that two additional products were also formed: the dlacatate oi 3-hydroxymethylcaranol-4 /I/ and the bicyclic ether 2,24lmethyl-6_rethylene-3-oxabicyclo-[3.3.1.]-nonane /III/.5 \ P + CB20 ' IV x Part VI: Rocznlkl Chem.

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