Ternary redox systems as initiators for the graft polymerization of polycaproamide with dimethylaminoethyl methacrylate
β Scribed by M. S. Kislyuk; G. A. Gabrielyan; M. V. Alekseeva; L. S. Gal'braikh
- Publisher
- Springer US
- Year
- 1984
- Tongue
- English
- Weight
- 280 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0015-0541
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Polymerization of methyl methacrylate using H20, with poly(ethylene oxide) having xanthate groups, was carried out to yield methyl methacrylate-ethylene oxide block copolymers. Principal parameters affecting the synthesis were examined. Block copolymers were characterized by spectroscopic methods.
stable than 12. Structural reasons for this tendency can be found from the X-ray structure analyses of 9, 13, and 16. In these structures the 0-H ... 0 distances between the phenolate oxygen atoms and the aqua ligands are 2.72 (9), 2.70 (13), and 2.68 A (16). The 0 ... 0 distances within one triangu