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Ternary Cr(III)-nucleotide-amino acid complexes: L-methionine, L-serine and glycine derivatives

✍ Scribed by A.M. Calafat; J.J. Fiol; A. Terron; V. Moreno; D.M.L. Goodgame; I. Hussain


Book ID
107901253
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
73 KB
Volume
36
Category
Article
ISSN
0162-0134

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Metal complexes of biologically importan
✍ Roland KrΓ€mer; Kurt Polborn; Christian Robl; Wolfgang Beck πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 606 KB

## Elimination of chloride from Cp\*Rh(L-PheO)Cl with AgBF, leads to the trinuclear complex [Cp\*Rh(p-L-Phe0)],3+(BF4-)3 (Z), in which the amino acidate acts both as an (N, 0)-chelating and as a carboxylate bridging ligand according to the X-ray structural determination. Trimerization of [Cp\*Rh(P