Termolecular recombination rate, microscopic reversibility and faddeev theory
β Scribed by T.K. Lim; J.M. Yuan; M.I. Haftel
- Book ID
- 103019038
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 438 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Exact Faddeev theory and microscopic reversibility are applied to the description of termolecular recombination in a model system of three helium-like atoms. Our results indicate that experimentally determined values of ka(T) can be repro-duced_
π SIMILAR VOLUMES
Recombination reactions of radicals generated by photolysis are often analyzed by considering the reactive dynamics of an isolated geminate pair. However, when the concentration of photodissociated radical pairs is high, the recombination of nongeminate radicals should also be taken into account. Th
The recombination of methyl radicals in low pressures of hydrogen, helium, and nitrogen to form ethane controls the concentrations observed for methyl and the photochemical synthesis of higher hydrocarbons above the Jovian planets. Few measured or theoretical rate constants are available to provide