Terbium Polyoxometalate Organic Complexes: Correlation of Structure with Luminescence Properties

Structural and Magnetic Properties of Mn

Structural and Magnetic Properties of MnIII and CuII Tetranuclear Azido Polyoxometalate Complexes: Multifrequency High-Field EPR Spectroscopy of Cu4 Clusters with S=1 and S=2 Ground States

✍ Pierre Mialane; Carole Duboc; Jérôme Marrot; Eric Rivière; Anne Dolbecq; Francis 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 303 KB 👁 1 views

## Abstract Two new azido‐bridged polyoxometalate compounds were synthesized in acetonitrile/methanol media and their molecular structures have been determined by X‐ray crystallography. The [{(γ‐SiW~10~O~36~)Mn~2~(OH)~2~(N~3~)~0.5~(H~2~O)~0.5~}~2~(μ‐1,3‐N~3~)]^10−^ (1 a) tetranuclear Mn^III^ comple