Template synthesis of macrocyclic compounds

✍ Scribed by Nikolaĭ Vasilʹevich Gėrbėlėu; V B Arion; John Burgess

• Publisher: Wiley-VCH
• Year: 1999
• Tongue: English
• Leaves: 579
• Category: Library

✦ Synopsis

The synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical.  Read more... Template Synthesis of Macrocyclic Compounds; Contents; 1 Template processes; 2 Template synthesis of polyazamacrocyclic compounds; 3 Template synthesis of macrocyclic systems based on di- and polyamines, and polyfunctional dicarbonyl compounds; 4 Template synthesis of three-dimensional macrocyclic systems; 5 Phosphorus- and arsenic-containing macrocyclic compounds; 6 Crown ethers and related compounds; 7 Covalent template synthesis; 8 Polynucleating macrocyclic compounds; 9 Other macrocyclic compounds; 10 Uses of template processes and products; 11 Conclusions

✦ Table of Contents

Template Synthesis of Macrocyclic Compounds......Page 1
Contents......Page 9
1.1 Introduction......Page 13
1.2 Fundamental terms and notions......Page 16
1.3 Mechanistic aspects of the template effect......Page 18
1.4 Generation of metal-free macrocycles......Page 23
1.5 Transmetallation......Page 25
1.6 Template particle types for obtaining different ligand products......Page 26
1.7 The place of metal template processes among other chemical reactions with participation of metal ions......Page 33
1.8 Classification of macrocyclic compounds......Page 36
1.9 References......Page 38
2.1 Cyclic hydrazines and hydrazones......Page 41
2.2 Hexa- and pentaazamacrocyclic systems based on chalcogensemicarbazides......Page 50
2.3 Nickel(II) octaazamacrocyclic complexes based on thiocarbohydrazide......Page 73
2.4 Hexaazacyclotetradecine compounds containing azo groups......Page 77
2.5 Saturated polyazamacrocyclic compounds......Page 89
2.6 Tetra- and hexaazamacrocyclic complexes derived from diamines and bifunctional carbonyl compounds......Page 108
2.7 Macrocyclic complexes with ligands based on 1,3-dicarbonyl compounds and 1,2- or 1,3-diamines......Page 119
2.8 Macrocyclic systems based on aromatic o-aminocarbonyl compounds and their derivatives......Page 141
2.9.1 Porphyrins and related compounds......Page 166
2.9.2 Corrins......Page 177
2.9.3 Phthalocyanines......Page 182
2.10 References......Page 199
3.1 Macrocycles based on 2,6-dicarbonylpyridines, 2,5-diformylpyrrole and the simplest diamines......Page 213
3.2 Macrocycles based on 2,6-dicarbonylpyridines and 1,n–diamines containing an additional supporting donor atom......Page 230
3.3 Macrocycles based on 2,6-dicarbonylpyridines and diamines containing two additional supporting donor atoms......Page 243
3.4 Macrocycles based on 2,6-dicarbonylpyridines and diamines containing three additional supporting donor atoms......Page 259
3.5 Macrocycles derived from 2,6-dicarbonylpyridines, 2,5- diformylpyrrole and 1,3-diaminopropan-2-ol......Page 265
3.6 Macrocycles derived from 2,5-diformylfuran, 2,5-diformylthiophene and 1,n-diamines......Page 272
3.7 References......Page 277
4.1.1 Clathrochelates based on 1,2- and 1,3-diaminoalkanes......Page 283
4.1.2 Macrobicyclic tris(mono- and di-)oximates and other cage complexes......Page 301
4.1.3 Siderophore models and cryptands......Page 317
4.2.1 Introduction......Page 326
4.2.2 Threading: pseudorotaxanes......Page 328
4.2.3 Rotaxanes......Page 338
4.2.4 Catenanes......Page 344
4.2.5 Knots......Page 377
4.3 References......Page 386
5.1 Phosphorus......Page 397
5.2 Arsenic......Page 408
5.3 References......Page 411
6.1 Crown ethers......Page 413
6.2 Thiacrown ethers......Page 431
6.3 Heterocrown ethers......Page 440
6.4 References......Page 457
7.1 Macrocyclic polylactones, polylactams and related compounds......Page 463
7.2 References......Page 474
8.1 Binucleating systems based on 4-substituted 2,6-dicarbonylphenol derivatives and simple diamines......Page 477
8.2 Binucleating systems based on 4-substituted 2,6-dicarbonylphenol derivatives and diamines containing additional donor atoms or groups......Page 491
8.3 Polynucleating macrocycles bearing soft and hard metal-binding sites......Page 509
8.4 Polynucleating systems with space-separated metal-binding sites......Page 520
8.5 References......Page 529
9.1 Isothiocarbazide- and/or oxime-based macrocycles, calixarenes, metallamacrocycles......Page 535
9.2 References......Page 551
10.1 Applications......Page 553
10.2 References......Page 558
11 Conclusions......Page 563