Template-Induced and Molecular Recognition Directed Hierarchical Generation of Supramolecular Assemblies from Molecular Strands
β Scribed by Volker Berl; Michael J. Krische; Ivan Huc; Jean-Marie Lehn; Marc Schmutz
- Book ID
- 102679164
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 729 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0947-6539
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π SIMILAR VOLUMES
Recognition processes occuring at the molecular level may lead to changes at the level of the material, thus expressing molecular information on the macroscopic scale. This is the case namely when the formation of a complementary supramolecular pair E 3 induces the appearance of a liquid crystalline
β¦ (depicted here and in the native city of the two Chinese authors), but p-stacked columns can be built up by p-stacked metallocyclophanes, which self-assemble upon coordination of homoditopic p-conjugated systems linked to U-shaped, bimetallic, Cu I molecular clips that are stabilized by bridging p
Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho