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Template and Guest Effects on the Self-Assembly of a Neutral and Homochiral Helix

โœ Scribed by Frank M. Tabellion; S. Russell Seidel; Atta M. Arif; Peter J. Stang


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
149 KB
Volume
40
Category
Article
ISSN
0044-8249

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โœฆ Synopsis


Coordination-driven assembly based on manganese(II) centers and flexible 1,3-bis(4-pyridyl)propane leads to the solid-state formation of electronically neutral, self-templated homochiral helices, closed ring structures, and racemic mixtures of helices depending upon the presence or absence of guests such as benzene and 1,2-diphenylethane.


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