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Temperature-Variable FTIR and Solid-State 13C NMR Investigations on Crystalline Structure and Molecular Dynamics of Polymorphic Poly(l-lactide) and Poly(l-lactide)/Poly(d-lactide) Stereocomplex

โœ Scribed by Pan, Pengju; Yang, Jinjun; Shan, Guorong; Bao, Yongzhong; Weng, Zhixue; Cao, Amin; Yazawa, Koji; Inoue, Yoshio


Book ID
115482491
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
577 KB
Volume
45
Category
Article
ISSN
0024-9297

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The effects of crystallinity, water absorption, hydrolytic degradation, and tacticity on the solid structure and chain mobility of poly(lactide)s were investigated by solid-state 13 C NMR spectroscopy. The following results were obtained from the line shapes of the carbonyl and methine carbons in 13