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Temperature study of the intramolecular interactions in 15-crown-5 and 18-crown-6

✍ Scribed by G. Georgiev; J. Nikolov; Zh. Nickolov; V. Zhelyaskov


Book ID
108008684
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
535 KB
Volume
47
Category
Article
ISSN
1386-1425

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Complexes of Lanthanoid Nitrates with 15
✍ Jean-Claude G. BΓΌnzli; Denis Wessner πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 German βš– 860 KB

Complexes between the heavier lanthanoid nitrates Ln(NO~3~)~3~ and 15‐crown‐5 (**1**) and 18‐crown‐6 (**2**) ethers were isolated and characterized. Both 1:1 and 4:3 complexes are formed with each Ln(III) ion, except in the case of Gd and **2**. The thermal transformation of the 1:1 complexes into t