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Temperature reversible IR spectral changes and site structure dynamics for SeF6 isolated in krypton matrices

✍ Scribed by Llewellyn H. Jones; B.I. Swanson; S.A. Ekberg


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
229 KB
Volume
74
Category
Article
ISSN
0009-2614

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✦ Synopsis


FTlR results for SeF6 trapped m a krypton matnx exhibit dramatlc temperature reversible spectral changes for the mnPlex ~3 structure. The spectral changes are believed to result from dynamic exchange among low symmetry trappmg sites on the mfrared tune scale to give an effective site symmetry change