𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Temperature-Responsive Water-Soluble Copolymers Based on 2-Hydroxyethyl Acrylate and Butyl Acrylate

✍ Scribed by Grigoriy A. Mun; Zauresh S. Nurkeeva; Aliya B. Beissegul; Artem V. Dubolazov; Perizat I. Urkimbaeva; Kinam Park; Vitaliy V. Khutoryanskiy

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
191 KB
Volume
208
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Amphiphilic copolymers have been synthesised by free radical copolymerisation of 2‐hydroxyethyl acrylate with butyl acrylate, the reactivity ratios of which indicate practically equal reactivity. The copolymers containing less than 30 mol‐% of BA were soluble in water and exhibited a LCST in aqueous solutions. It was found that the interaction between these copolymers and poly(acrylic acid) in aqueous solutions resulted in the formation of interpolymer complexes stabilised by hydrogen bonds and hydrophobic interactions. This interaction was significantly affected by solution pH and led to modification of the temperature‐responsive behaviour of the copolymers.

magnified image

πŸ“œ SIMILAR VOLUMES

Conducting composite films based on poly
Conducting composite films based on polypyrrole and crosslinked poly(styrene-butyl acrylate-hydroxyethyl acrylate)
✍ Wusheng Yin; Hongwu Liu; Jun Li; Yongming Li; Tiren Gu πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 137 KB πŸ‘ 2 views

Polypyrrole/crosslinked poly(styrene-butyl acrylate-hydroxyethyl acrylate) (PSBH) conductive composite films were designed to obtain high conductivity and good mechanical properties, and were prepared by vapor-phase polymerization of pyrrole within the silicon-crosslinked PSBH network using anhydrou

Mechanical properties of hydrophilic cop
Mechanical properties of hydrophilic copolymers of 2-hydroxyethyl methacrylate with ethyl acrylate,n-butyl acrylate, and dodecyl methacrylate
✍ Kola?οΏ½k, Jan ;Migliaresi, Claudio πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 571 KB

Copolymers were prepared of 2-hydroxyethyl methacrylate, which is strongly hydrophilic, with hydrophobic comonomers having a low glass transition temperature, i.e., ethyl acrylate, n-butyl acrylate, and dodecyl methacrylate. The glass transition temperature, T, (1 Hz), of polymers in the dry state (

Hydrogels based on gelatin poly(hydroxye
Hydrogels based on gelatin poly(hydroxyethyl methacrylate) and poly(butyl acrylate) graft copolymer impregnated with fibrin
✍ P. Ravindra Babu; T.P. Sastry; C. Rose; N. Muralidhara Rao πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 123 KB πŸ‘ 2 views

Gelatin was graft copolymerized with poly(hydroxyethyl methacrylate and butyl acrylate) and subsequently crosslinked with glutaraldehyde. Fibrin of bovine origin was incorporated onto this graft copolymer and characterized for the percentage of grafting. The infrared spectroscopy, mechanical strengt