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Temperature-programmed desorption study of the oxidation of methanol to formaldehyde on TiO2(110)-supported vanadia monolayers

✍ Scribed by G.S. Wong; D.D. Kragten; J.M. Vohs


Book ID
117214842
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
148 KB
Volume
452
Category
Article
ISSN
0039-6028

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Density functional theory was used to study the mechanism for the oxidation of methanol to formaldehyde. A vanadium oxide cluster OΒΌ ΒΌV(OH) 3 has been utilized to represent the catalytic system under hydrated conditions, i.e., in the presence of VΓ€ Γ€OH hydroxyl groups. Two types of methoxy-intermedi