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Temperature-Induced Solid-State Valence Tautomeric Interconversion in Two Cobalt−Schiff Base Diquinone Complexes

✍ Scribed by Cador, Olivier; Chabre, Françoise; Dei, Andrea; Sangregorio, Claudio; Slageren, Joris Van; Vaz, Maria G. F.


Book ID
121507603
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
124 KB
Volume
42
Category
Article
ISSN
0020-1669

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An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio