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Temperature-Induced Phase Transition of Well-Defined Cyclic Poly( N -isopropylacrylamide)s in Aqueous Solution

✍ Scribed by Qiu, Xing-Ping; Tanaka, Fumihiko; Winnik, Françoise M.


Book ID
121858264
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
83 KB
Volume
40
Category
Article
ISSN
0024-9297

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Time-resolved fluorescence anisotropy measurements have been performed upon an acenaphthylenelabelled (0.5 tool%) sample of poly(N-isopropylacrylamide), PNIPAM, in dilute solutions in both methanol and water as solvents. In methanol, segmental relaxation of PNIPAM follows an Arrhenius dependence upo