Temperature effect on the steric course of the acdi-catalysed solvolysis of aryloxiranes. A relationship between the enthalpic and the entropic contents of the transition states and the stereoselectivity.
β Scribed by Carlo Battistini; Paolo Crotti; Franco Macchia
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 250 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Nucleophilic substitution in poly(vinyl chloride) (PVC) with sodium thiobenzoate (NaTBZ) has been studied in two kinds of solvent. From the evolution of the content of isotactic (mr) and heterotactic (mr) triads in the unmodified parts of the polymer, as investigated by 13C n.m.r., the reaction was