Successive phase transitions in CsBi(MoO 4 ) 2 at 125 and 325 K have been studied by Raman spectroscopy. The changes in the crystal structure, induced by the low-temperature first-order transition, have been discussed. The found anomalous shifts of some internal modes towards lower frequency with de
β¦ LIBER β¦
Temperature-dependent polarized Raman spectra of CaFe2O4
β Scribed by N. Kolev; M.N. Iliev; V.N. Popov; M. Gospodinov
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 360 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0038-1098
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β¦ Synopsis
The Raman spectra of CaFe 2 O 4 were measured with several exact scattering configurations between 20 and 520 K and the symmetry of all observed Raman lines was determined. The A g and B 2g lines were assigned to definite phonon modes by comparison to the results of lattice dynamical calculations. No anomaly of phonon parameters was observed near the magnetic ordering temperature T N ΒΌ 160 K:
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