Temperature-dependent hyperfine coupling constants in electron spin resonance. 5. Amino group rotation in the cation of diaminodurene
✍ Scribed by A.T Bullock; C.B Howard
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 416 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-2364
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The temperature dependences of hydroxyl group proton and ring proton isotropic hyperÐne coupling constants (IHFC) of 1,4-hydroquinone (HQ) and 1,4-dihydroxynaphthalene (NQ) cation radicals were measured by electron paramagnetic resonance spectroscopy. The spectral parameters were obtained in the tem
## Abstract Temperature dependence of __cis__‐ and __trans__‐vicinal spin‐spin coupling constants of substituted cyclic 5‐membered compounds is discussed. The temperature dependence of __trans__‐vicinal coupling constants is shown to be essentially stronger than that of __cis__‐vicinal coupling con