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Temperature dependent electron relaxation time in the photo-excited triplet state of pyrene-d-10

✍ Scribed by L.J. Sims; A.V. Guzzo; A.B. Denison

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 326 KB
Volume: 5
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)85169-7

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✦ Synopsis

Ternpernture dependent ESR relaxation measurements made on the excited triplet state of pyrene-d-10 show ;L decrease in Tie with decrease in temperature from 300°K to SOOK. Optical measurements suggest the relnxation arises from exciton motion in the host crystal fluorene.

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The orlentatlon and temperature dependence of the spm-lattwze relauatlon rate m the photoevnted tnplet sfafe of pyrene-d,,, m a Ruorene cr)istaI was measured usrng the Saturalmn method The onenfafmn dependence supports the hypothesis rhat the relaxarlon arises from strong amsotropx hbratlons coupled