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Temperature Dependence of Water Interactions with the Amide Carbonyls of α-Helices

✍ Scribed by Brewer, Scott H.; Tang, Yuefeng; Vu, Dung M.; Gnanakaran, S.; Raleigh, Daniel P.; Dyer, R. Brian

Book ID
126899626
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
932 KB
Volume
51
Category
Article
ISSN
0006-2960

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The reactions of enamines with sulfoxides bearing a-hydrogens in the presence of a magnesium amide, generated in situ from the reaction of ethylmagnesium bromide with diisopropylamine. afforded the corresponding a-sulfenylalkylated ketones and aldehydes in isolated yields ranging from 39 to 76%. Thi